鲁西地区矽卡岩型铜金矿He—Ar同位素测定及其地质意义——以沂南地区铜井式铜金矿为例          下载免费PDF全文

祝德成  田瑞聪  田京祥  于学峰  杨振毅  杨仕鹏 《山东国土资源》2018,34(8)

铜井式铜金矿(包括铜井铜金矿、金场铜金矿)是鲁西地区发现和开采最早、矿化最普遍的矽卡岩型铜金矿。该文通过矿床的He-Ar同位素测试分析,并结合前人的H,O,S,C稳定同位素分析和年代学测试结果,对铜井式铜金矿成因及成矿机制进行探讨。研究认为,铜井式金矿主要形成于燕山晚期(128~121Ma),黄铁矿中流体包裹体的~(3 )He/~(4 )He值为0.112 9~0.120 9R/Ra,高于地壳物质值,低于典型地幔物质值;~(40 )Ar/~(36 )Ar=364.1~458.0,高于大气值,低于地幔值,成矿流体中存在来源于地壳的放射成因Ar;~(4 )He/~(40 )Ar=1.16~3.433,平均2.296 5,略高于地幔值(1.36~2.23),低于典型地壳值(6.4),表明成矿流体中存在地幔He,Ar;同时有地壳He,Ar加入。综上认为,矿床成矿物质和流体具有深源特征,应来自地幔或下地壳,金成矿主要是与燕山晚期浅成—超浅成中酸性侵入岩有关,这些侵入体在侵位过程中与古生代碳酸盐岩地层发生接触交代作用,形成矽卡岩型铜金矿床。  相似文献   

OCEANOGRAPHY & MARINE GEOLOGY     

《Abstract of Chinese Geological Literature》2014,(3)

正20141271Chang Fengming(Key Laboratory of Marine Geology and Environment,Institute of Oceanology,Chinese Academy of Sciences,Qingdao 266071,China);Li Tiegang Progress in the Paleoceanography of the Western Pacific Warm Pool:A Review(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(8),2013,p.847-858,3 illus.,108 refs.)Key words:paleooceanography,West Pacific  相似文献   

Stable isotopes of water show deep seasonal recharge in northern bogs and fens          下载免费PDF全文

Zeno F. Levy  Donald I. Siegel  Soumitri S. Dasgupta  Paul H. Glaser  Jeffrey M. Welker 《水文研究》2014,28(18):4938-4952

Ground water recharge is assumed to occur primarily at raised bog crests in northern peatlands, which are globally significant terrestrial carbon reservoirs. We synoptically surveyed vertical profiles of peat pore water δ¹⁸O and δ²H from a range of bog and fen landforms across the Glacial Lake Agassiz Peatlands, northern Minnesota. Contrary to our expectations, we find that local‐scale recharge penetrates to not only the basal peat at topographically high bog crests but also transitional Sphagnum lawns and low‐lying fen water tracks. Surface landscape characteristics appear to control the isotopic composition of the deeper pore waters (depths ≥0.5 m), which are partitioned into discrete ranges of δ¹⁸O on the basis of landform type (mean ± standard deviation for bog crests = ?11.9 ± 0.4‰, lawns = ?10.6 ± 0.1‰, fen water tracks = ?8.8 ± 1.0‰). Fen water tracks have a shallow free‐water surface that is seasonally enriched by isotope fractionating evaporation, fingerprinting recharge to underlying pore waters at depths ≥3 m. Isotope mass balance calculations indicate on average 12% of the waters we sampled from the basal peat of the fen water tracks was lost to surface evaporation, which occurred prior to advection and dispersion into the underlying formation. These new data provide direct support for the hypothesis that methane production in deeper peat strata is fuelled by the downward transport of labile carbon substrates from the surface of northern peat basins. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

长江口盐度梯度下不同形态碳的分布、来源与混合行为   总被引：1，自引：0，他引：1  

叶君  姚鹏  徐亚宏  王金鹏  赵彬 《海洋学报》2019,41(4):15-26

河口碳的生物地球化学过程是全球碳循环的重要组成。通过测定溶解无机碳（DIC）及其稳定同位素丰度（δ13C_DIC），溶解有机碳（DOC），有色溶解有机物（CDOM），颗粒有机碳（POC）及其稳定同位素丰度（δ13C_POC）与元素比值（N/C）及相关指标，研究了2014年7月长江口盐度梯度下不同形态碳的分布、来源和混合行为。结果表明，DIC浓度、DOC浓度、POC含量分别为1 583.2~1 739.6 μmol/L，128.4~369.4 μmol/L和51.2~530.8 μmol/L，这些不同形态碳及CDOM的荧光组分的分布模式相似，均是从口内到口外，整体呈现先增大后减小的趋势，并与盐度呈现非保守混合行为。添加作用主要发生在在口门处最大浑浊带附近。与含量相反，从口内到口外，δ13C_DIC和δ13C_POC均呈现逐渐减小再增大的趋势，在口门附近达到最低值，分别为-9.7‰和-26.7‰。在口门附近不同形态碳含量上升及δ13C_DIC、δ13C_POC的降低可能主要与沉积物再悬浮及微生物作用有关。基于蒙特卡洛模拟的三端元混合模型的结果显示，河口内外POC来源变化明显，口内POC以陆源有机碳贡献为主，平均为62.3%，口外海源贡献逐渐增加。CDOM相关参数结果表明长江口CDOM主要来自陆源输入，海源及人类活动等也对其产生影响。  相似文献   

利用水系沉积物高程定量恢复古地貌的技术方法——以鲁西白彦地区白彦砾岩为例          下载免费PDF全文

程光锁  于学峰  杨斌  胡戈  李兆营  周军  刘卫东  罗文强  马祥县 《山东国土资源》2019,35(9)

主要分析了构造抬升对水系和地形的影响和恢复,以从古生代灰岩围岩中大面积但零星出露的岩溶砾岩点为研究对象,对区域古水系和地形地貌恢复和反演做出了新的尝试。在收集资料和实测的基础上,尝试性探讨了利用稳定水体参照物高程反演抬升高度以及邻区山峰点的古高程、古水系,恢复区域上古地形地貌的技术方法。并以白彦地区为例,通过白彦岩溶砾岩的分布、产状、金刚石矿物含量、岩性等地质特征,恢复白彦地区古地形线、古水系位置和流向等古地理地貌,指出在白彦期时代,该区总体发育4个水系,邹城市大石墙水系、枣庄水系、平邑水系、费县水系,水系中金刚石含量较为丰富的砾岩点大多分布在凤凰山隆起中心,其中在平邑水系推测存在一个山地峡谷中的古湖泊。认为蒙山凸起中已知的常马庄地区的金伯利岩脉所含有金刚石可能主要供应平邑区水系,其他3个地区水系的金刚石可能来源于凤凰山及其东部隆起剥蚀地区。  相似文献   

Assessing basin storage: Comparison of hydrometric- and tracer-based indices of dynamic and total storage     

Ciara D. Cooke  James M. Buttle 《水文研究》2020,34(9):2012-2031

Storage is a fundamental but elusive component of drainage basin function, influencing synchronization between precipitation input and streamflow output and mediating basin sensitivity to climate and land use/land cover (LULC) change. We compare hydrometric and isotopic approaches to estimate indices of dynamic and total basin storage, respectively, and assess inter-basin differences in these indices across the Oak Ridges Moraine (ORM) region of southern Ontario, Canada. Dynamic storage indices for the 20 study basins included the ratio of baseflow to total streamflow (baseflow index BFI), Q ₉₉ flow and flow duration curve (FDC) slope. Ratios of the standard deviation of the streamflow stable isotope signal relative to that of precipitation were determined for each basin from a 1 year bi-weekly sampling program and used as indicators of total storage. Smaller ratios imply longer water travel times, smaller young water fractions (F _yw, < ~2–3 months in age) in streamflow and greater basin storage. Ratios were inversely related to BFI and Q ₉₉, and positively related to FDC slope, suggesting longer travel times and smaller F _yw for basins with stable baseflow-dominated streamflow regimes. Inter-basin differences in all indices reflected topographic, hydrogeologic and LULC controls on storage, which was greatest in steep, forest-covered headwaters underlain by permeable deposits with thick and relatively uniform unsaturated zones. Nevertheless, differential sensitivity of indices to controls on storage indicates the value of using several indices to capture more completely how basin characteristics influence storage. Regression relationships between storage indices and basin characteristics provided reasonable predictions of aspects of the streamflow regime of test basins in the ORM region. Such relationships and the underlying knowledge of controls on basin storage in this landscape provide the foundation for initial predictions of relative differences in streamflow response to regional changes in climate and LULC.  相似文献   

Identification of groundwater mean transit times of precipitation and riverbank infiltration by two‐component lumped parameter models     

Nguyen Le Duy  Nguyen Viet Dung  Ingo Heidbüchel  Hanno Meyer  Markus Weiler  Bruno Merz  Heiko Apel 《水文研究》2019,33(24):3098-3118

Groundwater transit time is an essential hydrologic metric for groundwater resources management. However, especially in tropical environments, studies on the transit time distribution (TTD) of groundwater infiltration and its corresponding mean transit time (mTT) have been extremely limited due to data sparsity. In this study, we primarily use stable isotopes to examine the TTDs and their mTTs of both vertical and horizontal infiltration at a riverbank infiltration area in the Vietnamese Mekong Delta (VMD), representative of the tropical climate in Asian monsoon regions. Precipitation, river water, groundwater, and local ponding surface water were sampled for 3 to 9 years and analysed for stable isotopes (δ¹⁸O and δ²H), providing a unique data set of stable isotope records for a tropical region. We quantified the contribution that the two sources contributed to the local shallow groundwater by a novel concept of two‐component lumped parameter models (LPMs) that are solved using δ¹⁸O records. The study illustrates that two‐component LPMs, in conjunction with hydrological and isotopic measurements, are able to identify subsurface flow conditions and water mixing at riverbank infiltration systems. However, the predictive skill and the reliability of the models decrease for locations farther from the river, where recharge by precipitation dominates, and a low‐permeable aquitard layer above the highly permeable aquifer is present. This specific setting impairs the identifiability of model parameters. For river infiltration, short mTTs (<40 weeks) were determined for sites closer to the river (<200 m), whereas for the precipitation infiltration, the mTTs were longer (>80 weeks) and independent of the distance to the river. The results not only enhance the understanding of the groundwater recharge dynamics in the VMD but also suggest that the highly complex mechanisms of surface–groundwater interaction can be conceptualized by exploiting two‐component LPMs in general. The model concept could thus be a powerful tool for better understanding both the hydrological functioning of mixing processes and the movement of different water components in riverbank infiltration systems.  相似文献   

Spatially distributed tracer‐aided modelling to explore water and isotope transport,storage and mixing in a pristine,humid tropical catchment          下载免费PDF全文

Joni Dehaspe  Christian Birkel  Doerthe Tetzlaff  Ricardo Sánchez‐Murillo  Ana María Durán‐Quesada  Chris Soulsby 《水文研究》2018,32(21):3206-3224

Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km² San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.  相似文献   

三氟乙酸锂-15-冠醚-5体系电迁移法分离锂同位素          下载免费PDF全文

黄超驰  孙进贺  张茜  张鹏瑞  汪词明  薛子轩  景燕  贾永忠 《盐湖研究》2021,29(3):83-89

锂同位素(~6Li和~7Li)在核工业中有着重要作用。锂汞齐法是目前唯一实现锂同位素工业化生产的方法,然而由于汞的使用,该方法具有较大的环境风险。开发绿色高效的锂同位素分离方法对国家能源安全具有重要意义。在本论文中,制备了溶解锂盐的冠醚溶液,并以其作为阳极液,施加电场驱动锂离子向阴极液迁移;与溶有15-冠醚-5的锂盐水溶液作为阳极液相比,研究发现在阳极液体系中引入水分子可以促进锂同位素的分离。同时还考察了不同隔膜对锂同位素分离的影响,发现使用强疏水性隔膜时,短时间内有较好的分离效应。  相似文献   

新疆阿尔泰别也萨麻斯稀有金属矿床含矿伟晶岩与花岗岩围岩成因关系     

丁建刚  杨成栋  杨富全  李强 《地球科学与环境学报》2020,(1):71-85

别也萨麻斯矿床是目前新发现的分布在新疆北阿尔泰以Li矿化为主的花岗伟晶岩型稀有金属矿床,具有独特性和代表性。矿区发育Li-Nb-Ta矿化和Nb-Ta矿化两类伟晶岩,二云母二长花岗岩是含矿伟晶岩脉群的直接围岩。在系统的野外地质特征调查(包括野外露头和钻孔岩芯赋矿岩系、矿化特征、蚀变类型等的详细观察)基础上,对含矿伟晶岩和二云母二长花岗岩开展了LA-ICP-MS锆石U-Pb定年和原位Hf同位素研究。获得锆石206Pb/238U加权平均年龄分别为(151.0±1.8)Ma和(449.0±4.2)Ma,含矿伟晶岩形成于晚侏罗世,二云母二长花岗岩则形成于晚奥陶世。含矿伟晶岩和二云母二长花岗岩的εHf(t)值分别为0.62~1.30和1.35~6.07,二阶段Hf模式年龄为1161~1118 Ma和1345~1037 Ma。含矿伟晶岩的εHf(t)值较花岗岩小得多,二阶段Hf模式年龄与形成年龄的差值较花岗岩大得多,表明两者是阿尔泰造山带在不同演化阶段下的产物。悬殊的年龄差、不同的大地构造背景与不同的形成物源表明别也萨麻斯稀有金属矿床含矿伟晶岩与二云母二长花岗岩在成因上并无联系,近矿花岗岩围岩并非含矿伟晶岩脉的真正母体。  相似文献